Choose which email address to use to send an email message

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* Open outlook

* Click on “New” to compose a new message

* Select the “Options” tab on the top ribbon

* Select the “From” button in “Show Fields”
From Button in outlook

* The “From” button will now appear above the “To” button, click on it and then select “Other E-mail Address”
From Button in outlook 2

* Enter the E-mail address you would like to send as.

The above method will require the user to have send as permission, check with your system administrator if you are unsure.